Page 228 - Chemistry ICSE Class X
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214                                                                                     ICSE Chemistry – 10
                                           Experiment to Show that Hydrogen Chloride is

                                           Heavier than Air
                                           Perform the following activity to show that hydrogen chloride gas is
                                           heavier than air:


                Aim: To show that hydrogen chloride gas is heavier than air
             ACTIVITY 1  Materials required:   ũĂƌ ĮůůĞĚ ǁŝƚŚ , ů ŐĂƐ͕ ĂŶ ĞŵƉƚLJ ;ĚƌLJͿ ŐĂƐ ũĂƌ͕ ŐůĂƐƐ ƌŽĚ
                Procedure: &ŽůůŽǁ ƚŚĞ ĨŽůůŽǁŝŶŐ ƐƚĞƉƐ͗
                    ƒ  WůĂĐĞ Ă ĚƌLJ ĞŵƉƚLJ ŐĂƐ ũĂƌ ŽŶ ƚŚĞ ƚĂďůĞ͘

                    ƒ    ƌŝŶŐ Ă ŐůĂƐƐ ƌŽĚ ĚŝƉƉĞĚ ŝŶ ĂŵŵŽŶŝƵŵ ŚLJĚƌŽdžŝĚĞ ŶĞĂƌ ƚŚŝƐ ũĂƌ͘ KďƐĞƌǀĞ

                     ŝĨ ĂŶLJ ǁŚŝƚĞ ĨƵŵĞƐ ĂƌĞ ĨŽƌŵĞĚ͘
                    ƒ  EŽ ǁŚŝƚĞ ĨƵŵĞƐ ĂƌĞ ƐĞĞŶ ĂƌŽƵŶĚ ƚŚĞ ŐůĂƐƐ ƌŽĚ͘
                    ƒ  ^ŚŝŌ ƚŚĞ ĞŵƉƚLJ ŐĂƐ ũĂƌ ƐŽŵĞ ĚŝƐƚĂŶĐĞ ĂǁĂLJ ĨƌŽŵ ŝƚƐ ƉŽƐŝƟŽŶ͘
                    ƒ   EŽǁ ďƌŝŶŐ Ă ŐĂƐ ũĂƌ ĮůůĞĚ ǁŝƚŚ , ů ;ŐĂƐͿ ŶĞĂƌ ƚŚĞ ŵŽƵƚŚ ŽĨ ƚŚĞ ŽƚŚĞƌ ŐĂƐ
                     ũĂƌ ĂŶĚ ŚŽůĚ ŝƚ ƐůĂŶƟŶŐ ĚŽǁŶǁĂƌĚƐ ĨŽƌ Ă ĨĞǁ ŵŝŶƵƚĞƐ͘
                    ƒ  ZĞŵŽǀĞ ƚŚĞ ŐĂƐ ũĂƌ ǁŚŝĐŚ ĐŽŶƚĂŝŶĞĚ ƚŚĞ , ů ŐĂƐ͘
                    ƒ   ƌŝŶŐ ƚŚĞ ŐůĂƐƐ ƌŽĚ ĚŝƉƉĞĚ ŝŶ ĂŵŵŽŶŝĂ ŶĞĂƌ ƚŚĞ ŵŽƵƚŚ ŽĨ ƚŚĞ ůŽǁĞƌ ũĂƌ͘ KďƐĞƌǀĞ͘
                    ƒ  tŚŝƚĞ ĨƵŵĞƐ ĂƌĞ ƐĞĞŶ ŶĞĂƌ ƚŚĞ ŵŽƵƚŚ ŽĨ ƚŚĞ ŐůĂƐƐ ũĂƌ ĂŶĚ ĂƌŽƵŶĚ ƚŚĞ ŐůĂƐƐ ƌŽĚ͘
                KďƐĞƌǀĂƟŽŶ͗ dŚĞ ůŽǁĞƌ ŐĂƐ ũĂƌ ŶŽǁ ĐŽŶƚĂŝŶĞĚ , ů ŐĂƐ͘
                 ŽŶĐůƵƐŝŽŶ͗ , ů ŐĂƐ ŝƐ ƚƌĂŶƐĨĞƌƌĞĚ ƚŽ ƚŚĞ ůŽǁĞƌ ũĂƌ ƐŚŽǁŝŶŐ ƚŚĂƚ , /;gͿ ŝƐ ŚĞĂǀŝĞƌ ƚŚĂŶ Ăŝƌ͘


                                           What are the chemical properties of hydrogen chloride

                                           Dry liquid hydrogen chloride does not react with metals, such as zinc,
                                           iron, magnesium and with quicklime and some carbonates.
                                                Aluminium, however, gets dissolved in liquid hydrogen chloride
                                           liberating hydrogen gas.
                                                Most chemical properties of HCl described below, in fact, are the
                                           properties of its solution in water (hydrochloric acid).
                                             ƒ  Combustibility. Hydrogen chloride is neither combustible nor a
                                                supporter of combustion.
                                             ƒ  Thermal stability. On heating above 500°C, it decomposes into
                                                hydrogen and chlorine.
                                             ƒ  Acidic nature. Perfectly dry HCl gas does not affect litmus paper,
                                                but in the presence of water, it turns blue litmus red. In aqueous
                                                                                          +
                                                solution, it ionises to give hydronium (H O ),
                                                                                        3
                                                                                   +
                                                                                              –
                                                 HCl(g)    +   H O(l)  o H O (aq) +  Cl (aq)
                                                                 2
                                                                                3
                                                                       +
                                               It is because of this H O  that in chemical reactions, HCl(aq) behaves
                                                                     3
                                                like a typical acid.
                                             ƒ  Action with ammonia. With ammonia gas, HCl(aq) gives dense white
                                                fumes of ammonium chloride.
                                                 NH (g) +  HCl(aq)  o         NH Cl
                                                     3
                                                                                   4
                                                                            dense white fumes
                                             ƒ  With carbonates and hydrogencarbonates. HCl(aq) decomposes
                                                carbonates and hydrogencarbonates (bicarbonates) to give CO  gas,
                                                                                                             2
                                                 Na CO  +  2HCl(aq)  o 2NaCl(aq) +  H O +  CO (g)
                                                                                                           2
                                                                                               2
                                                    2
                                                        3
                                               sodium carbonate                                        carbon dioxide
                                                 NaHCO  +  HCl(aq)  o NaCl(aq)           + H O +  CO (g)
                                                                                                           2
                                                         3
                                                                                               2
                                            sodium hydrogencarbonate
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