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126                                                                                     ICSE Chemistry – 10

                                                    ASSIGNMENT 2

                          Normal temperature and pressure, Standard temperature and pressure, Gay-Lussac’s law of
                                combining volumes, Avogadro’s law, Atomicity, Applications of Avogadro’s law

              ϭ͘  tŚĂƚ ŝƐ ŵĞĂŶƚ ďLJ
                  ;ĂͿ  EŽƌŵĂů ƚĞŵƉĞƌĂƚƵƌĞ ĂŶĚ ƉƌĞƐƐƵƌĞ ;EdWͿ͍
                  ;ďͿ  ^ƚĂŶĚĂƌĚ ƚĞŵƉĞƌĂƚƵƌĞ ĂŶĚ ƉƌĞƐƐƵƌĞ ;^dWͿ͍
              Ϯ͘  ;ĂͿ  ^ƚĂƚĞ 'ĂLJͲ>ƵƐƐĂĐ͛Ɛ ůĂǁ ŽĨ ĐŽŵďŝŶŝŶŐ ǀŽůƵŵĞƐ͘
                  ;ďͿ  'ŝǀĞ ĂŶ ĞdžĂŵƉůĞ ƚŽ ŝůůƵƐƚƌĂƚĞ ƚŚĞ ĂďŽǀĞ ůĂǁ͘
              ϯ͘    ŵŝdžƚƵƌĞ ĐŽŶƚĂŝŶŝŶŐ ϲ ůŝƚƌĞƐ ŽĨ ŚLJĚƌŽŐĞŶ ĂŶĚ ϱ͘ϲ ůŝƚƌĞƐ ŽĨ ĐŚůŽƌŝŶĞ ŝƐ ĞdžƉůŽĚĞĚ͘ tŚĂƚ ǁŝůů ďĞ ƚŚĞ ĐŽŵƉŽƐŝƟŽŶ ;ďLJ ǀŽůƵŵĞͿ
                ŽĨ ƚŚĞ ƌĞƐƵůƟŶŐ ŐĂƐĞŽƵƐ ŵŝdžƚƵƌĞ͍                                           [Ans. V;, ůͿ с ϭϭ͘Ϯ >͕ V;, Ϳ с Ϭ͘ϰ >]
                                                                                                           Ϯ
              ϰ͘  ϱϬϬ ŵ> ŽĨ ŶŝƚƌŝĐ ŽdžŝĚĞ ŝƐ ƌĞĂĐƚĞĚ ǁŝƚŚ ϯϬϬ ŵ> ŽĨ ŽdžLJŐĞŶ ƚŽ ĨŽƌŵ ŶŝƚƌŽŐĞŶ ĚŝŽdžŝĚĞ͘ tŚĂƚ ǁŽƵůĚ ďĞ ƚŚĞ ĐŽŵƉŽƐŝƟŽŶ ŽĨ ƚŚĞ
                ƌĞĂĐƟŽŶ ŵŝdžƚƵƌĞ͍                                                    [Ans. V;EK Ϳ с ϱϬϬ ŵ>͕ V;ƵŶƵƐĞĚ K Ϳ с ϱϬ ŵ>]
                                                                                                           Ϯ
                                                                                           Ϯ
              ϱ͘  ^ƚĂƚĞ  ǀŽŐĂĚƌŽ͛Ɛ ůĂǁ͘
              ϲ͘  tŚĂƚ ŝƐ ŵĞĂŶƚ ďLJ  ǀŽŐĂĚƌŽ͛Ɛ ĐŽŶƐƚĂŶƚ͍ tŚĂƚ ŝƐ ŝƚƐ ǀĂůƵĞ͍
              ϳ͘  ;ĂͿ  tŚĂƚ ŝƐ ŵŽůĂƌ ǀŽůƵŵĞ͍
                  ;ďͿ  tŚĂƚ ŝƐ ƚŚĞ ŵŽůĂƌ ǀŽůƵŵĞ ŽĨ Ă ŐĂƐ ƵŶĚĞƌ EdW ĐŽŶĚŝƟŽŶƐ͍
              ϴ͘  ;ĂͿ  tŚĂƚ ŝƐ ƚŚĞ ĂƚŽŵŝĐŝƚLJ ŽĨ പപ;ŝͿ ƉŚŽƐƉŚŽƌƵƐ പപ;ŝŝͿ ŽdžLJŐĞŶ പപ;ŝŝŝͿ ƐƵůƉŚƵƌ͍
                  ;ďͿ  tƌŝƚĞ ƚŚĞ ŵĂƚŚĞŵĂƟĐĂů ĨŽƌŵƵůĂ ǁŚŝĐŚ ƌĞůĂƚĞƐ ǀĂƉŽƵƌ ĚĞŶƐŝƚLJ ŽĨ Ă ŐĂƐĞŽƵƐ ƐƵďƐƚĂŶĐĞ ƚŽ ŝƚƐ ŵŽůĞĐƵůĂƌ ŵĂƐƐ͘
              ϵ͘  hŶĚĞƌ ƐŝŵŝůĂƌ ĐŽŶĚŝƟŽŶƐ ŽĨ ƚĞŵƉĞƌĂƚƵƌĞ ĂŶĚ ƉƌĞƐƐƵƌĞ͕ Ϯ > ŽĨ ĐĂƌďŽŶ ĚŝŽdžŝĚĞ͕ ϯ > ŽĨ ĐŚůŽƌŝŶĞ͕ ϱ > ŽĨ ŚLJĚƌŽŐĞŶ͕ ϰ > ŽĨ
                ŶŝƚƌŽŐĞŶ ĂŶĚ ϭ > ŽĨ ƐƵůƉŚƵƌ ĚŝŽdžŝĚĞ ĂƌĞ ƚĂŬĞŶ͘ tŚŝĐŚ ŽĨ ƚŚĞƐĞ ƐĂŵƉůĞƐ ǁŝůů ŚĂǀĞ
                  ;ĂͿ  ƚŚĞ ŵĂdžŝŵƵŵ ŶƵŵďĞƌ ŽĨ ŵŽůĞĐƵůĞƐ
                  ;ďͿ  ƚŚĞ ůĞĂƐƚ ŶƵŵďĞƌ ŽĨ ŵŽůĞĐƵůĞƐ͘
             ϭϬ͘  ϱϬϬ ŵ> ŽĨ ŚLJĚƌŽŐĞŶ ĐŽŶƚĂŝŶƐ n ŵŽůĞĐƵůĞƐ͘ ,Žǁ ŵĂŶLJ ŵŽůĞĐƵůĞƐ ŽĨ ŽdžLJŐĞŶ ǁŝůů ďĞ ƉƌĞƐĞŶƚ ŝŶ ϮϱϬ ŵ> ŽĨ ŽdžLJŐĞŶ ƵŶĚĞƌ
                ƐŝŵŝůĂƌ ĐŽŶĚŝƟŽŶƐ ŽĨ ƚĞŵƉĞƌĂƚƵƌĞ ĂŶĚ ƉƌĞƐƐƵƌĞ͍                                             [Ans. nͬϮ]

                                           Atomic Mass and Relative Atomic Mass

                                           Atom is the smallest particle which takes part in a chemical reaction. A
                                           molecule is the smallest unit of any substance which can exist independently,
                                           and shows all the properties of that substance. Each molecule is a group of
                                           chemically bonded atoms.
                                                Each atom or a molecule has its own characteristic mass. So, the atomic
                                           and molecular masses may be expressed in any unit of mass, i.e., in gram,
                                           kilograms, etc. But the actual mass of a single atom is very small. An atom
                                           of hydrogen (the lightest atom) is 0.000  000  000  000  000  000  000  000  001
                                           673 kg (1.673 × 10 –27  kg). It is not possible to measure such small masses
                                           even with the help of the most sensitive balance. Such small numbers are
                                           not very convenient to write also.
                                                IUPAC accepted in 1961 the atomic mass unit scale to be used for
                                           expressing atomic and molecular masses. In this scale of atomic masses,
                                              12
                                           the  C isotope has been assigned an atomic mass of 12.000000 atomic mass
                                               6
                                           units.
                                           What is the atomic mass unit
                                           Atomic masses are very small. To express atomic masses, a unit called
          dŚĞ ĂƚŽŵŝĐ ŵĂƐƐ ƵŶŝƚ ŝƐ ĂďďƌĞǀŝĂƚĞĚ   atomic mass unit (abbreviation, amu; symbol, u) is commonly used. The
          ĂƐ amu͕ ĂŶĚ ĚĞŶŽƚĞĚ ďLJ ƚŚĞ ƐLJŵďŽů
          Ƶ͕ Žƌ ŵ ͘ tĞ ĂƌĞ ƵƐŝŶŐ ƚŚĞ ƐLJŵďŽů Ƶ   CVQOKE OCUU WPKV KU FGſPGF CU HQNNQYU
                u
                                                                                      12
                                                                   1
          ĨŽƌ ĂƚŽŵŝĐ ŵĂƐƐ ƵŶŝƚ ŝŶ ƚŚŝƐ Ŭ͘    The mass equal to  th of the mass of a  C atom is called one atomic
                                                                                       6
                                                                  12
                                           mass unit.
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