Page 223 - Chemistry ICSE Class IX
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Chemistry Practicals                                                                                 211

                      'ZRGTKOGPV                        Observations                        Inference
                                               %122'4 ++  57.2*#6' *;&4#6'
           ™  Observe the salt and its colour  ™  The given salt is a blue crystalline  ™  May be a salt of copper(II).
                                                substance.
           ™  Heat the salt and identify the gas   ™  On heating, blue crystals crumble  ™  May be copper sulphate.
             evolved                            into white amorphous powder.
           ™  Examine the residue            ™  Steamy vapour is given out.     ™  The salt is a hydrated salt.
           ™  Drop the liquid condensed on   ™  The vapour gets condensed on the  ™  May be anhydrous copper
             the upper part of the test tube on   cooler parts of the test tube giving   sulphate.
             white residue                      a colourless liquid.            ™  The colourless liquid condensed
                                             ™  White amorphous powder.            on the upper part of the test tube
                                             ™  White residue turns blue.          is water.
          Result:  ™  The given salt is EQRRGT ++  UWNRJCVG RGPVCJ[FTCVG  %W51 .5H 1
                                                                         4   2
                  ™ Residue is EQRRGT ++  UWNRJCVG  %W51
                                                       4
                                                  '
                                   .
          Result:            CuSO 5H O(s)       o           CuSO (s)         +       5H O(l)
                                      2
                                  4
                                                                    4
                                                                                         2
                             copper(II) sulphate            copper(II) sulphate         water
                               pentahydrate
                                             %122'4 ++  0+64#6' *':#*;&4#6'
           ™  Observe the salt and its colour  ™  Bluish-green crystalline solid  ™  It may be a salt of copper(II).
           ™  Heat the salt and identify the   ™  On heating, it
             gases evolved                         y melts to form a bluish-green
                                                  mass.
                                                   y gives off steamy vapour which   ™  The given salt is a hydrated salt.
                                                  condenses on the cooler parts
                                                  of the test tube to form droplets
                                                  of water.
           ™  Examine the residue            ™  On heating strongly,
                                                   y the bluish-green mass changes   ™  The black residue is EQRRGT ++
                                                  to a black residue.              oxide.
                                                   y it gives off a reddish-brown   ™  The evolved gaseous mixture
                                                  gas and rekindles a glowing      contains NO  and O .
                                                                                                     2
                                                                                              2
                                                  splinter.
                                                                         .
          Result:  ™  The given salt is EQRRGT ++  PKVTCVG JGZCJ[FTCVG =%W 01   6H O]
                                                                       3 2
                                                                            2
                                                 heat
                                     .
          Reaction:          Cu(NO ) 6H O       o          Cu(NO ) (s)       +       6H O(l)
                                                                    3 2
                                                                                         2
                                        2
                                   3 2
                              copper(II) nitrate            copper(II) nitrate          water
                               hexahydrate
                                              heat strongly
                               2Cu(NO )       o            2CuO(s)         +      4NO (g)      +    H O(g)
                                                                                           2
                                                                                                         2
                                      3 2
                              copper(II) nitrate          copper(II) oxide (black)      nitrogen dioxide
                                                   %122'4 ++  %#4$10#6'
           ™  Observe the salt and its colour  ™  Light green amorphous powder.  ™  It may be a salt of Cu(II) or Ni(II).
           ™  Heat the salt and identify the   ™  On heating, it gives off a    ™  The evolved gas is CO .
                                                                                                       2
             gases evolved                      colourless and odourless gas,
                                                which turns limewater milky.
           ™  Examine the residue            ™  Black powdery substance.        ™  It may be copper(II) oxide (CuO).
                                                                                ™  6JG IKXGP UCNV KU EQRRGT ++
                                                                                   carbonate.
                                                 heat
          Reaction:            CuCO (s)         o            CuO(s)          +       CO (g)
                                                                                          2
                                     3
                             copper(II) carbonate            copper(II) oxide        carbon dioxide
                                                                                  (turns limewater milky)
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